Symmetry selection rules for reaction mechanisms: Application to metal-ligand isomerizations

Alison Rodger; Pieter E. Schipper

Symmetry selection rules for reaction mechanisms: Application to metal-ligand isomerizations

Alison Rodger^*, Pieter E. Schipper

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The recently developed CSR (classical selection rule) procedure is developed specifically for application to isomerization reactions between structures with the same point symmetry (homoconversions) and those of different point symmetry (heteroconversions). For homoconversions, a rigorous procedure for determining the product-generating relationship (the combined permutation-point operation relating the two isomers) is discussed. The CSR procedure is then applied to the systematic determination of the concerted reaction mechanisms of metal-ligand isomerizations of complexes of the form ML_n (n = 3-7) and M(LL)₃.

Original language	English
Pages (from-to)	458-466
Number of pages	9
Journal	Inorganic Chemistry
Volume	27
Issue number	3
Publication status	Published - 1988
Externally published	Yes

Bibliographical note

Erratum can be found in Inorganic Chemistry, 27(16), p. 2904, 1988.
https://doi.org/10.1021/ic00289a035

Cite this

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title = "Symmetry selection rules for reaction mechanisms: Application to metal-ligand isomerizations",

abstract = "The recently developed CSR (classical selection rule) procedure is developed specifically for application to isomerization reactions between structures with the same point symmetry (homoconversions) and those of different point symmetry (heteroconversions). For homoconversions, a rigorous procedure for determining the product-generating relationship (the combined permutation-point operation relating the two isomers) is discussed. The CSR procedure is then applied to the systematic determination of the concerted reaction mechanisms of metal-ligand isomerizations of complexes of the form MLn (n = 3-7) and M(LL)3.",

author = "Alison Rodger and Schipper, {Pieter E.}",

note = "Erratum can be found in Inorganic Chemistry, 27(16), p. 2904, 1988. https://doi.org/10.1021/ic00289a035",

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T1 - Symmetry selection rules for reaction mechanisms

T2 - Application to metal-ligand isomerizations

AU - Rodger, Alison

AU - Schipper, Pieter E.

N1 - Erratum can be found in Inorganic Chemistry, 27(16), p. 2904, 1988. https://doi.org/10.1021/ic00289a035

PY - 1988

Y1 - 1988

N2 - The recently developed CSR (classical selection rule) procedure is developed specifically for application to isomerization reactions between structures with the same point symmetry (homoconversions) and those of different point symmetry (heteroconversions). For homoconversions, a rigorous procedure for determining the product-generating relationship (the combined permutation-point operation relating the two isomers) is discussed. The CSR procedure is then applied to the systematic determination of the concerted reaction mechanisms of metal-ligand isomerizations of complexes of the form MLn (n = 3-7) and M(LL)3.

AB - The recently developed CSR (classical selection rule) procedure is developed specifically for application to isomerization reactions between structures with the same point symmetry (homoconversions) and those of different point symmetry (heteroconversions). For homoconversions, a rigorous procedure for determining the product-generating relationship (the combined permutation-point operation relating the two isomers) is discussed. The CSR procedure is then applied to the systematic determination of the concerted reaction mechanisms of metal-ligand isomerizations of complexes of the form MLn (n = 3-7) and M(LL)3.

UR - http://www.scopus.com/inward/record.url?scp=0010683812&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0010683812

SN - 0020-1669

VL - 27

SP - 458

EP - 466

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 3

ER -

Symmetry selection rules for reaction mechanisms: Application to metal-ligand isomerizations

Abstract

Bibliographical note

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