Syntheses and purification of the versatile synthons iodoferrocene and 1,1′-diiodoferrocene

Max Roemer; Christian A. Nijhuis

doi:10.1039/c4dt01787k

Syntheses and purification of the versatile synthons iodoferrocene and 1,1′-diiodoferrocene

Max Roemer, Christian A. Nijhuis^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

This paper describes the improved synthesis and purification of iodoferrocene (FcI) and 1,1′-diiodoferrocene (FcI₂). FcI and FcI₂ were prepared by mono- and dilithiation of ferrocene followed by conversion into iodoferrocenes by reaction with iodine. Purification was accomplished by a simple sublimation/distillation procedure, affording FcI and FcI₂ in high yields (74 and 72%) and high purity (>99.9%). We determined the molecular structures of FcI and FcI₂ by X-ray single crystal diffraction.

Original language	English
Pages (from-to)	11815-11818
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	31
DOIs	https://doi.org/10.1039/c4dt01787k
Publication status	Published - 21 Aug 2014
Externally published	Yes

Access to Document

10.1039/c4dt01787k

Cite this

@article{d2f00a74f8fc4523ba8afa49fc21739d,

title = "Syntheses and purification of the versatile synthons iodoferrocene and 1,1′-diiodoferrocene",

abstract = "This paper describes the improved synthesis and purification of iodoferrocene (FcI) and 1,1′-diiodoferrocene (FcI2). FcI and FcI2 were prepared by mono- and dilithiation of ferrocene followed by conversion into iodoferrocenes by reaction with iodine. Purification was accomplished by a simple sublimation/distillation procedure, affording FcI and FcI2 in high yields (74 and 72\%) and high purity (>99.9\%). We determined the molecular structures of FcI and FcI2 by X-ray single crystal diffraction. ",

author = "Max Roemer and Nijhuis, \{Christian A.\}",

year = "2014",

month = aug,

day = "21",

doi = "10.1039/c4dt01787k",

language = "English",

volume = "43",

pages = "11815--11818",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "31",

}

TY - JOUR

T1 - Syntheses and purification of the versatile synthons iodoferrocene and 1,1′-diiodoferrocene

AU - Roemer, Max

AU - Nijhuis, Christian A.

PY - 2014/8/21

Y1 - 2014/8/21

N2 - This paper describes the improved synthesis and purification of iodoferrocene (FcI) and 1,1′-diiodoferrocene (FcI2). FcI and FcI2 were prepared by mono- and dilithiation of ferrocene followed by conversion into iodoferrocenes by reaction with iodine. Purification was accomplished by a simple sublimation/distillation procedure, affording FcI and FcI2 in high yields (74 and 72%) and high purity (>99.9%). We determined the molecular structures of FcI and FcI2 by X-ray single crystal diffraction.

AB - This paper describes the improved synthesis and purification of iodoferrocene (FcI) and 1,1′-diiodoferrocene (FcI2). FcI and FcI2 were prepared by mono- and dilithiation of ferrocene followed by conversion into iodoferrocenes by reaction with iodine. Purification was accomplished by a simple sublimation/distillation procedure, affording FcI and FcI2 in high yields (74 and 72%) and high purity (>99.9%). We determined the molecular structures of FcI and FcI2 by X-ray single crystal diffraction.

UR - https://www.scopus.com/pages/publications/84904437697

U2 - 10.1039/c4dt01787k

DO - 10.1039/c4dt01787k

M3 - Article

C2 - 24999911

AN - SCOPUS:84904437697

SN - 1477-9226

VL - 43

SP - 11815

EP - 11818

JO - Dalton Transactions

JF - Dalton Transactions

IS - 31

ER -

Syntheses and purification of the versatile synthons iodoferrocene and 1,1′-diiodoferrocene

Abstract

Access to Document

Other files and links

Fingerprint

Cite this