Synthesis of novel ruthenium complexes containing bidentate imidazole-based ligands

Sarah Elgafi, Leslie D. Field, BA Messerle, Trevor W. Hambley, Peter Turner

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Ruthenium(II) complexes containing the bidentate imidazole-based ligands (MeN2H2C3)(2)CO L-1, (MeN2H2C3)(2)CHOH L-2 and (MeN2H2C3)(2)CH2 L-3 (where 1-MeN2H2C3 = 1-methylimidazol-2-yl), [Ru(PPh3)(2)H(CO)L-1]Cl 1, [Ru(PPh3)(2)H(CO)L-2]Cl 2 and [Ru(PPh3)(2)H(CO)L-3]Cl 3, were synthesized by the reaction of L-1-L-3 with [Ru(PPh3)(3)H(Cl)(CO)] in toluene. The complexes were characterised by NMR spectroscopy and the crystal structures of [Ru(PPh3)(2)H(CO)L-1]BF4 4 and [Ru(PPh3)(2)H(CO)L-2]OH 5 determined.

    Original languageEnglish
    Pages (from-to)2341-2345
    Number of pages5
    JournalDalton Transactions
    Issue number13
    Publication statusPublished - 7 Jul 1997

    Keywords

    • SPECTROSCOPIC PROPERTIES
    • CARBONIC-ANHYDRASE
    • CRYSTAL-STRUCTURE
    • ZINC ENZYMES
    • CHEMISTRY
    • MODELS
    • DERIVATIVES
    • REACTIVITY
    • DIOXYGEN

    Fingerprint

    Dive into the research topics of 'Synthesis of novel ruthenium complexes containing bidentate imidazole-based ligands'. Together they form a unique fingerprint.

    Cite this