Synthesis of novel ruthenium complexes containing bidentate imidazole-based ligands

Sarah Elgafi; Leslie D. Field; BA Messerle; Trevor W. Hambley; Peter Turner

Synthesis of novel ruthenium complexes containing bidentate imidazole-based ligands

Sarah Elgafi, Leslie D. Field, BA Messerle, Trevor W. Hambley, Peter Turner

Department of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

Ruthenium(II) complexes containing the bidentate imidazole-based ligands (MeN2H2C3)(2)CO L-1, (MeN2H2C3)(2)CHOH L-2 and (MeN2H2C3)(2)CH2 L-3 (where 1-MeN2H2C3 = 1-methylimidazol-2-yl), [Ru(PPh3)(2)H(CO)L-1]Cl 1, [Ru(PPh3)(2)H(CO)L-2]Cl 2 and [Ru(PPh3)(2)H(CO)L-3]Cl 3, were synthesized by the reaction of L-1-L-3 with [Ru(PPh3)(3)H(Cl)(CO)] in toluene. The complexes were characterised by NMR spectroscopy and the crystal structures of [Ru(PPh3)(2)H(CO)L-1]BF4 4 and [Ru(PPh3)(2)H(CO)L-2]OH 5 determined.

Original language	English
Pages (from-to)	2341-2345
Number of pages	5
Journal	Dalton Transactions
Issue number	13
Publication status	Published - 7 Jul 1997

Keywords

SPECTROSCOPIC PROPERTIES
CARBONIC-ANHYDRASE
CRYSTAL-STRUCTURE
ZINC ENZYMES
CHEMISTRY
MODELS
DERIVATIVES
REACTIVITY
DIOXYGEN

Cite this

@article{3854777d2c8a489ba8e5f597b0aeac87,

title = "Synthesis of novel ruthenium complexes containing bidentate imidazole-based ligands",

abstract = "Ruthenium(II) complexes containing the bidentate imidazole-based ligands (MeN2H2C3)(2)CO L-1, (MeN2H2C3)(2)CHOH L-2 and (MeN2H2C3)(2)CH2 L-3 (where 1-MeN2H2C3 = 1-methylimidazol-2-yl), [Ru(PPh3)(2)H(CO)L-1]Cl 1, [Ru(PPh3)(2)H(CO)L-2]Cl 2 and [Ru(PPh3)(2)H(CO)L-3]Cl 3, were synthesized by the reaction of L-1-L-3 with [Ru(PPh3)(3)H(Cl)(CO)] in toluene. The complexes were characterised by NMR spectroscopy and the crystal structures of [Ru(PPh3)(2)H(CO)L-1]BF4 4 and [Ru(PPh3)(2)H(CO)L-2]OH 5 determined.",

keywords = "SPECTROSCOPIC PROPERTIES, CARBONIC-ANHYDRASE, CRYSTAL-STRUCTURE, ZINC ENZYMES, CHEMISTRY, MODELS, DERIVATIVES, REACTIVITY, DIOXYGEN",

author = "Sarah Elgafi and Field, {Leslie D.} and BA Messerle and Hambley, {Trevor W.} and Peter Turner",

year = "1997",

month = jul,

day = "7",

language = "English",

pages = "2341--2345",

journal = "Dalton Transactions",

issn = "1477-9234",

publisher = "Royal Society of Chemistry",

number = "13",

}

TY - JOUR

T1 - Synthesis of novel ruthenium complexes containing bidentate imidazole-based ligands

AU - Elgafi, Sarah

AU - Field, Leslie D.

AU - Messerle, BA

AU - Hambley, Trevor W.

AU - Turner, Peter

PY - 1997/7/7

Y1 - 1997/7/7

N2 - Ruthenium(II) complexes containing the bidentate imidazole-based ligands (MeN2H2C3)(2)CO L-1, (MeN2H2C3)(2)CHOH L-2 and (MeN2H2C3)(2)CH2 L-3 (where 1-MeN2H2C3 = 1-methylimidazol-2-yl), [Ru(PPh3)(2)H(CO)L-1]Cl 1, [Ru(PPh3)(2)H(CO)L-2]Cl 2 and [Ru(PPh3)(2)H(CO)L-3]Cl 3, were synthesized by the reaction of L-1-L-3 with [Ru(PPh3)(3)H(Cl)(CO)] in toluene. The complexes were characterised by NMR spectroscopy and the crystal structures of [Ru(PPh3)(2)H(CO)L-1]BF4 4 and [Ru(PPh3)(2)H(CO)L-2]OH 5 determined.

AB - Ruthenium(II) complexes containing the bidentate imidazole-based ligands (MeN2H2C3)(2)CO L-1, (MeN2H2C3)(2)CHOH L-2 and (MeN2H2C3)(2)CH2 L-3 (where 1-MeN2H2C3 = 1-methylimidazol-2-yl), [Ru(PPh3)(2)H(CO)L-1]Cl 1, [Ru(PPh3)(2)H(CO)L-2]Cl 2 and [Ru(PPh3)(2)H(CO)L-3]Cl 3, were synthesized by the reaction of L-1-L-3 with [Ru(PPh3)(3)H(Cl)(CO)] in toluene. The complexes were characterised by NMR spectroscopy and the crystal structures of [Ru(PPh3)(2)H(CO)L-1]BF4 4 and [Ru(PPh3)(2)H(CO)L-2]OH 5 determined.

KW - SPECTROSCOPIC PROPERTIES

KW - CARBONIC-ANHYDRASE

KW - CRYSTAL-STRUCTURE

KW - ZINC ENZYMES

KW - CHEMISTRY

KW - MODELS

KW - DERIVATIVES

KW - REACTIVITY

KW - DIOXYGEN

M3 - Article

SP - 2341

EP - 2345

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9234

IS - 13

ER -