Synthesis, structure and ionic conductivity of La2/3-xLi3xMoO4

Kai Jiang; Haixia Wang; Yinzhe Ren; Chongfeng Guo; Jian Meng; Yufang Ren; Qiang Su

Synthesis, structure and ionic conductivity of La_2/3-xLi_3xMoO₄

Kai Jiang^*, Haixia Wang, Yinzhe Ren, Chongfeng Guo, Jian Meng, Yufang Ren, Qiang Su

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A series of compounds, La_2/3-xLi_3xMoO₄ were prepared. Their structures are tetragonal scheelites with the cationic defects. The cell parameters a, c and values of c/a decrease with the increasing of the substitution amount (3x) of lithium ion. Cationic vacancies are getting more as Li⁺ concentration is lower. The diffusion of lithium ion is predominant. The concentration of charge carriers increases with the increase of the substitution amount (3x) of lithium ion, meanwhile, the concentration of cationic vacancies decreases. The conductivity approaches the best when the substitution amount (3x) of lithium ion is about 0.3. The conductivity of La_0.567Li_0.3MoO₄ is 6.5×10^-6 S · cm^-1 at room temperature.

Original language	English
Pages (from-to)	458-460
Number of pages	3
Journal	Journal of Rare Earths
Volume	21
Issue number	4
Publication status	Published - 2003

Keywords

Inorganic material chemistry
Ionic conduction
Lithium ion conductor
Rare earth molybdate
Rare earths

Cite this

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title = "Synthesis, structure and ionic conductivity of La2/3-xLi3xMoO4 ",

abstract = "A series of compounds, La2/3-xLi3xMoO4 were prepared. Their structures are tetragonal scheelites with the cationic defects. The cell parameters a, c and values of c/a decrease with the increasing of the substitution amount (3x) of lithium ion. Cationic vacancies are getting more as Li+ concentration is lower. The diffusion of lithium ion is predominant. The concentration of charge carriers increases with the increase of the substitution amount (3x) of lithium ion, meanwhile, the concentration of cationic vacancies decreases. The conductivity approaches the best when the substitution amount (3x) of lithium ion is about 0.3. The conductivity of La0.567Li0.3MoO4 is 6.5×10-6 S · cm-1 at room temperature.",

keywords = "Inorganic material chemistry, Ionic conduction, Lithium ion conductor, Rare earth molybdate, Rare earths",

author = "Kai Jiang and Haixia Wang and Yinzhe Ren and Chongfeng Guo and Jian Meng and Yufang Ren and Qiang Su",

year = "2003",

language = "English",

volume = "21",

pages = "458--460",

journal = "Journal of Rare Earths",

issn = "1002-0721",

publisher = "Elsevier",

number = "4",

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TY - JOUR

T1 - Synthesis, structure and ionic conductivity of La2/3-xLi3xMoO4

AU - Jiang, Kai

AU - Wang, Haixia

AU - Ren, Yinzhe

AU - Guo, Chongfeng

AU - Meng, Jian

AU - Ren, Yufang

AU - Su, Qiang

PY - 2003

Y1 - 2003

N2 - A series of compounds, La2/3-xLi3xMoO4 were prepared. Their structures are tetragonal scheelites with the cationic defects. The cell parameters a, c and values of c/a decrease with the increasing of the substitution amount (3x) of lithium ion. Cationic vacancies are getting more as Li+ concentration is lower. The diffusion of lithium ion is predominant. The concentration of charge carriers increases with the increase of the substitution amount (3x) of lithium ion, meanwhile, the concentration of cationic vacancies decreases. The conductivity approaches the best when the substitution amount (3x) of lithium ion is about 0.3. The conductivity of La0.567Li0.3MoO4 is 6.5×10-6 S · cm-1 at room temperature.

AB - A series of compounds, La2/3-xLi3xMoO4 were prepared. Their structures are tetragonal scheelites with the cationic defects. The cell parameters a, c and values of c/a decrease with the increasing of the substitution amount (3x) of lithium ion. Cationic vacancies are getting more as Li+ concentration is lower. The diffusion of lithium ion is predominant. The concentration of charge carriers increases with the increase of the substitution amount (3x) of lithium ion, meanwhile, the concentration of cationic vacancies decreases. The conductivity approaches the best when the substitution amount (3x) of lithium ion is about 0.3. The conductivity of La0.567Li0.3MoO4 is 6.5×10-6 S · cm-1 at room temperature.

KW - Inorganic material chemistry

KW - Ionic conduction

KW - Lithium ion conductor

KW - Rare earth molybdate

KW - Rare earths

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M3 - Article

AN - SCOPUS:1442303307

SN - 1002-0721

VL - 21

SP - 458

EP - 460

JO - Journal of Rare Earths

JF - Journal of Rare Earths

IS - 4

ER -

Synthesis, structure and ionic conductivity of La_2/3-xLi_3xMoO₄

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