Synthesis, structure and ionic conductivity of La2/3-xLi3xMoO4

Kai Jiang*, Haixia Wang, Yinzhe Ren, Chongfeng Guo, Jian Meng, Yufang Ren, Qiang Su

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review


    A series of compounds, La2/3-xLi3xMoO4 were prepared. Their structures are tetragonal scheelites with the cationic defects. The cell parameters a, c and values of c/a decrease with the increasing of the substitution amount (3x) of lithium ion. Cationic vacancies are getting more as Li+ concentration is lower. The diffusion of lithium ion is predominant. The concentration of charge carriers increases with the increase of the substitution amount (3x) of lithium ion, meanwhile, the concentration of cationic vacancies decreases. The conductivity approaches the best when the substitution amount (3x) of lithium ion is about 0.3. The conductivity of La0.567Li0.3MoO4 is 6.5×10-6 S · cm-1 at room temperature.

    Original languageEnglish
    Pages (from-to)458-460
    Number of pages3
    JournalJournal of Rare Earths
    Issue number4
    Publication statusPublished - 2003


    • Inorganic material chemistry
    • Ionic conduction
    • Lithium ion conductor
    • Rare earth molybdate
    • Rare earths


    Dive into the research topics of 'Synthesis, structure and ionic conductivity of La2/3-xLi3xMoO4'. Together they form a unique fingerprint.

    Cite this