The degree of charge-transfer in the ground-states of molecular π-complexes

R. J W Le Fèvre, D. V. Radford, P. J. Stiles

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Polarisation contributions to the dipole moments and binding energies of some typical molecular π-complexes are investigated. Normal van der Waals forces rather than charge-transfer interactions seem primarily responsible for these ground-state properties.

LanguageEnglish
Pages1297-1302
Number of pages6
JournalJournal of the Chemical Society B: Physical Organic
DOIs
Publication statusPublished - 1968
Externally publishedYes

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Van der Waals forces
Dipole moment
Binding energy
Ground state
Charge transfer
dipole moments
binding energy
charge transfer
Polarization
ground state
polarization
interactions
energy

Cite this

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title = "The degree of charge-transfer in the ground-states of molecular π-complexes",
abstract = "Polarisation contributions to the dipole moments and binding energies of some typical molecular π-complexes are investigated. Normal van der Waals forces rather than charge-transfer interactions seem primarily responsible for these ground-state properties.",
author = "{Le F{\`e}vre}, {R. J W} and Radford, {D. V.} and Stiles, {P. J.}",
year = "1968",
doi = "10.1039/J29680001297",
language = "English",
pages = "1297--1302",
journal = "Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry",
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}

The degree of charge-transfer in the ground-states of molecular π-complexes. / Le Fèvre, R. J W; Radford, D. V.; Stiles, P. J.

In: Journal of the Chemical Society B: Physical Organic, 1968, p. 1297-1302.

Research output: Contribution to journalArticleResearchpeer-review

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T1 - The degree of charge-transfer in the ground-states of molecular π-complexes

AU - Le Fèvre, R. J W

AU - Radford, D. V.

AU - Stiles, P. J.

PY - 1968

Y1 - 1968

N2 - Polarisation contributions to the dipole moments and binding energies of some typical molecular π-complexes are investigated. Normal van der Waals forces rather than charge-transfer interactions seem primarily responsible for these ground-state properties.

AB - Polarisation contributions to the dipole moments and binding energies of some typical molecular π-complexes are investigated. Normal van der Waals forces rather than charge-transfer interactions seem primarily responsible for these ground-state properties.

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DO - 10.1039/J29680001297

M3 - Article

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EP - 1302

JO - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry

T2 - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry

JF - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry

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