The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene

Adam D. Martin; Timothy L. Easun; Stephen P. Argent; William Lewis; Alexander J. Blake; Martin Schröder

doi:10.1039/c6ce01965j

The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene

Adam D. Martin, Timothy L. Easun, Stephen P. Argent, William Lewis, Alexander J. Blake, Martin Schröder

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Abstract

Two cyclotriveratrylene-based ligands H₃L¹ and H₃L² have been synthesised using microwave heating and used in the formation of 1 [Zn₂(L¹)(DMA)₂(CH₃COO)] and 2 [Zn₆(L²)₄(DMA)₆(H₂O)₅] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However, the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2.

Original language	English
Pages (from-to)	603-607
Number of pages	5
Journal	CrystEngComm
Volume	19
Issue number	4
DOIs	https://doi.org/10.1039/c6ce01965j
Publication status	Published - 2017
Externally published	Yes

Bibliographical note

Copyright The Royal Society of Chemistry 2017. Version archived for private and non-commercial use with the permission of the author/s and according to publisher conditions. For further rights please contact the publisher.

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10.1039/c6ce01965j

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title = "The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene",

abstract = "Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However, the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2.",

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doi = "10.1039/c6ce01965j",

language = "English",

volume = "19",

pages = "603--607",

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T1 - The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene

AU - Martin, Adam D.

AU - Easun, Timothy L.

AU - Argent, Stephen P.

AU - Lewis, William

AU - Blake, Alexander J.

AU - Schröder, Martin

N1 - Copyright The Royal Society of Chemistry 2017. Version archived for private and non-commercial use with the permission of the author/s and according to publisher conditions. For further rights please contact the publisher.

PY - 2017

Y1 - 2017

N2 - Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However, the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2.

AB - Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However, the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2.

UR - https://www.scopus.com/pages/publications/85010078543

U2 - 10.1039/c6ce01965j

DO - 10.1039/c6ce01965j

M3 - Article

SN - 1466-8033

VL - 19

SP - 603

EP - 607

JO - CrystEngComm

JF - CrystEngComm

IS - 4

ER -

The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene

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