The preparation, spectral properties and structure elucidations of the hitherto undocumented 3-oxo-, 3-thioxo-, 3-propylimino-, 3-imino-, and 3-propylamino- derivatives of 4-ethyl-2-propyl-2,3-dihydro-pyrrolo[3,4-b] quinoline-1,9-dione are described. Mechanistic aspects relating particularly to the formation of the latter two unprecedented products are considered. Magnetic anisotropic effects (deshielding/line broadening of signals) are exhibited by the α-methylene protons of the 4-ethyl moiety in the 1H NMR spectra of the first four of the above, and in several 3,3-dichloro-thieno[3,4- b]quinoline-1,9-diones and intramolecular H-bonded, 1,2-dialkyl-4-oxo-3- quinolinecarboxylic acid precursor substrates.
|Number of pages||8|
|Journal||South African Journal of Chemistry|
|Publication status||Published - 22 Sep 2006|