The synthesis of Chiral periodic organosilica materials with ultrasmall mesopores

Xiaowei Wu; Thomas Blackburn; Jonathan D. Webb; Alfonso E. Garcia-Bennett; Cathleen M. Crudden

doi:10.1002/anie.201101909

The synthesis of Chiral periodic organosilica materials with ultrasmall mesopores

Xiaowei Wu, Thomas Blackburn, Jonathan D. Webb, Alfonso E. Garcia-Bennett, Cathleen M. Crudden^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Helical organosilica materials were synthesized for the first time using a novel binaphthyl-based chiral co-monomer in less than 1 hour. The incorporation of a chiral co-monomer in the wall was shown to influence the curvature of the helical materials. As the amount of the chiral co-monomer was increased, the degree of curvature increased, illustrating the importance of this monomer to the overall morphology.

Original language	English
Pages (from-to)	8095-8099
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	35
DOIs	https://doi.org/10.1002/anie.201101909
Publication status	Published - 22 Aug 2011
Externally published	Yes

Keywords

chirality
helical structures
microporous materials
organosilica
silicon

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10.1002/anie.201101909

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abstract = "Helical organosilica materials were synthesized for the first time using a novel binaphthyl-based chiral co-monomer in less than 1 hour. The incorporation of a chiral co-monomer in the wall was shown to influence the curvature of the helical materials. As the amount of the chiral co-monomer was increased, the degree of curvature increased, illustrating the importance of this monomer to the overall morphology.",

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author = "Xiaowei Wu and Thomas Blackburn and Webb, {Jonathan D.} and Garcia-Bennett, {Alfonso E.} and Crudden, {Cathleen M.}",

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AU - Crudden, Cathleen M.

PY - 2011/8/22

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N2 - Helical organosilica materials were synthesized for the first time using a novel binaphthyl-based chiral co-monomer in less than 1 hour. The incorporation of a chiral co-monomer in the wall was shown to influence the curvature of the helical materials. As the amount of the chiral co-monomer was increased, the degree of curvature increased, illustrating the importance of this monomer to the overall morphology.

AB - Helical organosilica materials were synthesized for the first time using a novel binaphthyl-based chiral co-monomer in less than 1 hour. The incorporation of a chiral co-monomer in the wall was shown to influence the curvature of the helical materials. As the amount of the chiral co-monomer was increased, the degree of curvature increased, illustrating the importance of this monomer to the overall morphology.

KW - chirality

KW - helical structures

KW - microporous materials

KW - organosilica

KW - silicon

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JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 35

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The synthesis of Chiral periodic organosilica materials with ultrasmall mesopores

Abstract

Keywords

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