The thermal decomposition of octadeulerocyclobutane and octafliwrocyclobutane

B. F. Gray, H. O. Pritchard

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The high-pressure rate constant for the decomposition of [ 2H8]cyc/obutane at 443° is greater than that for ordinary cyclobutane and the fall-off of the rate constant takes place at a slightly higher pressure for the deuterated species. The decomposition of octafluorocyclobutane is shown to be a complex process unsuitable for testing theories of unimolecular reactions.

LanguageEnglish
Pages989-997
Number of pages9
JournalJournal of the Chemical Society (Resumed)
Publication statusPublished - 1956
Externally publishedYes

Fingerprint

Rate constants
Pyrolysis
Cyclobutanes
Decomposition
Testing
octafluorocyclobutane

Cite this

@article{5dad266e2e864a0c9b9a9b93278375ac,
title = "The thermal decomposition of octadeulerocyclobutane and octafliwrocyclobutane",
abstract = "The high-pressure rate constant for the decomposition of [ 2H8]cyc/obutane at 443° is greater than that for ordinary cyclobutane and the fall-off of the rate constant takes place at a slightly higher pressure for the deuterated species. The decomposition of octafluorocyclobutane is shown to be a complex process unsuitable for testing theories of unimolecular reactions.",
author = "Gray, {B. F.} and Pritchard, {H. O.}",
year = "1956",
language = "English",
pages = "989--997",
journal = "Journal of the Chemical Society (Resumed)",
issn = "0368-1769",
publisher = "Chemical Society",

}

The thermal decomposition of octadeulerocyclobutane and octafliwrocyclobutane. / Gray, B. F.; Pritchard, H. O.

In: Journal of the Chemical Society (Resumed), 1956, p. 989-997.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - The thermal decomposition of octadeulerocyclobutane and octafliwrocyclobutane

AU - Gray, B. F.

AU - Pritchard, H. O.

PY - 1956

Y1 - 1956

N2 - The high-pressure rate constant for the decomposition of [ 2H8]cyc/obutane at 443° is greater than that for ordinary cyclobutane and the fall-off of the rate constant takes place at a slightly higher pressure for the deuterated species. The decomposition of octafluorocyclobutane is shown to be a complex process unsuitable for testing theories of unimolecular reactions.

AB - The high-pressure rate constant for the decomposition of [ 2H8]cyc/obutane at 443° is greater than that for ordinary cyclobutane and the fall-off of the rate constant takes place at a slightly higher pressure for the deuterated species. The decomposition of octafluorocyclobutane is shown to be a complex process unsuitable for testing theories of unimolecular reactions.

UR - http://www.scopus.com/inward/record.url?scp=37049056016&partnerID=8YFLogxK

M3 - Article

SP - 989

EP - 997

JO - Journal of the Chemical Society (Resumed)

T2 - Journal of the Chemical Society (Resumed)

JF - Journal of the Chemical Society (Resumed)

SN - 0368-1769

ER -