Abstract
The high-pressure rate constant for the decomposition of [ 2H8]cyc/obutane at 443° is greater than that for ordinary cyclobutane and the fall-off of the rate constant takes place at a slightly higher pressure for the deuterated species. The decomposition of octafluorocyclobutane is shown to be a complex process unsuitable for testing theories of unimolecular reactions.
| Original language | English |
|---|---|
| Pages (from-to) | 989-997 |
| Number of pages | 9 |
| Journal | Journal of the Chemical Society (Resumed) |
| Publication status | Published - 1956 |
| Externally published | Yes |