Time-of-flight studies of electron-collection kinetics in polymer

fullerene bulk-heterojunction solar cells

Anthony J. Morfa*, Alexandre M. Nardes, Sean E. Shaheen, Nikos Kopidakis, Jao Van De Lagemaat

*Corresponding author for this work

Research output: Contribution to journalArticle

65 Citations (Scopus)

Abstract

The charge-collection dynamics in poly(3-hexylthiophene:[6,6]-phenyl-C 61-butyric acid methyl ester (P3HT:PCBM) bulk heterojunctions are studied in thick (>1 μm) devices using time-of-flight measurements and external quantum-efficiency measurements. The devices show Schottky-diode behavior with a large field-free region in the device. Consequently, electron transport occurs by diffusion in the bulk of the active layer. At high applied biases where the depletion region spans the entire active layer, normal time-of-flight transients are observed from which the electron mobility can be determined. Here, the electron mobility follows Poole-Frenkel behavior as a function of field. At lower applied biases, where the depletion region only spans a small portion of the active layer, due to a high density of dark holes, the recombination kinetics follow a first-order rate law with a rate constant about two orders of magnitude lower than that predicted by Langevin recombination. Transient photoconductivity measurements Schottky solar cells of poly(3-hexylthiophene:[6,6]-phenyl-C61-butyric acid methyl ester (P3HT:PCBM) at several voltages demonstrate the dependence of charge collection on transit time. The applied bias is controlled, which tunes the depletion layer width, and thus the field-free region. The total charge collected versus the average transit time is then calculated. First-order charge kinetics are demonstrated.

Original languageEnglish
Pages (from-to)2580-2586
Number of pages7
JournalAdvanced Functional Materials
Volume21
Issue number13
DOIs
Publication statusPublished - 8 Jul 2011
Externally publishedYes

Bibliographical note

Erratum can be found in Advanced Functional Materials, Volume 21(22), 4210, http://dx.doi.org/10.1002/adfm.201190099

Keywords

  • bulk heterojunctions
  • charge kinetics
  • organic photovoltaics
  • P3HT
  • time-of-flight

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