Abstract
Rotational relaxation of the ν4 = 1, J = 18, Ka = 11 state of D2CO is found to be faster than gas-kinetic and to involve multiple quantum changes in J within a single collision between D2CO molecules. The results conform to scaling laws based on |ΔJ| or the energy change |E| for the state-resolved molecule.
Original language | English |
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Pages (from-to) | 168-172 |
Number of pages | 5 |
Journal | Chemical Physics Letters |
Volume | 107 |
Issue number | 2 |
DOIs | |
Publication status | Published - 25 May 1984 |
Externally published | Yes |