Time-resolved infrared-ultraviolet double resonance studies of rotational relaxation in D2CO

B. J. Orr*, J. G. Haub, R. Haines

*Corresponding author for this work

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

Rotational relaxation of the ν4 = 1, J = 18, Ka = 11 state of D2CO is found to be faster than gas-kinetic and to involve multiple quantum changes in J within a single collision between D2CO molecules. The results conform to scaling laws based on |ΔJ| or the energy change |E| for the state-resolved molecule.

Original languageEnglish
Pages (from-to)168-172
Number of pages5
JournalChemical Physics Letters
Volume107
Issue number2
DOIs
Publication statusPublished - 25 May 1984
Externally publishedYes

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