Two-step regio- and stereoselective synthesis of cis-vinylstannanes

Paul Malek Mirzayans; Rebecca H. Pouwer; Craig M. Williams

doi:10.1021/ol801251m

Two-step regio- and stereoselective synthesis of cis-vinylstannanes

Paul Malek Mirzayans^*, Rebecca H. Pouwer, Craig M. Williams

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Herein we describe a novel stereoselective synthesis of cis-vinylstannanes employing the widely established Li/Te exchange pathway. In contrast to previously reported methods of cis-selective hydrostannation (i.e., ZrCI₄), this method demonstrates compatibility toward oxygenated substrates. (Figure presented in abstract)

Original language	English
Pages (from-to)	3861-3863
Number of pages	3
Journal	Organic Letters
Volume	10
Issue number	17
DOIs	https://doi.org/10.1021/ol801251m
Publication status	Published - 1 Sept 2008
Externally published	Yes

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10.1021/ol801251m

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title = "Two-step regio- and stereoselective synthesis of cis-vinylstannanes",

abstract = "Herein we describe a novel stereoselective synthesis of cis-vinylstannanes employing the widely established Li/Te exchange pathway. In contrast to previously reported methods of cis-selective hydrostannation (i.e., ZrCI4), this method demonstrates compatibility toward oxygenated substrates. (Figure presented in abstract) ",

author = "Mirzayans, {Paul Malek} and Pouwer, {Rebecca H.} and Williams, {Craig M.}",

year = "2008",

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T1 - Two-step regio- and stereoselective synthesis of cis-vinylstannanes

AU - Mirzayans, Paul Malek

AU - Pouwer, Rebecca H.

AU - Williams, Craig M.

PY - 2008/9/1

Y1 - 2008/9/1

N2 - Herein we describe a novel stereoselective synthesis of cis-vinylstannanes employing the widely established Li/Te exchange pathway. In contrast to previously reported methods of cis-selective hydrostannation (i.e., ZrCI4), this method demonstrates compatibility toward oxygenated substrates. (Figure presented in abstract)

AB - Herein we describe a novel stereoselective synthesis of cis-vinylstannanes employing the widely established Li/Te exchange pathway. In contrast to previously reported methods of cis-selective hydrostannation (i.e., ZrCI4), this method demonstrates compatibility toward oxygenated substrates. (Figure presented in abstract)

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U2 - 10.1021/ol801251m

DO - 10.1021/ol801251m

M3 - Article

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AN - SCOPUS:61349167777

SN - 1523-7060

VL - 10

SP - 3861

EP - 3863

JO - Organic Letters

JF - Organic Letters

IS - 17

ER -

Two-step regio- and stereoselective synthesis of cis-vinylstannanes

Abstract

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