Upper crustal differentiation processes and their role in 238U-230Th disequilibria at the San Pedro-Linzor volcanic chain (Central Andes)

U-series data are combined with major and trace element constraints to construct a detailed view of the magmatic system feeding the San Pedro-Linzor volcanic chain, aiding the understanding of how stratovolcanoes in extremely thick arc crust evolve. Lavas from the Quaternary San Pedro-Linzor volcanic chain (Central Andes) have (²³⁸U/²³⁰Th) ranging from 1.015 to 1.072, with ²³⁸U excess even in the less evolved (~57 wt% SiO₂) analyzed lavas. Contrary to well-established trends between fluid mobile elements and ²³⁸U excess, (²³⁸U/²³⁰Th)₀ shows no systematic correlation with ratios indicative of fluid-driven melting (e.g. Ba/Hf and K/La). Moreover, the inverse correlation between (²³⁸U/²³²Th) with the amount of slab-derived fluid and the oxidation state of the mantle below Central Andes, which decreases eastwards, suggests that the main control of the ²³⁸U excess is not associated with hydration of the mantle wedge. Changes in (²³⁸U/²³²Th) and (²³⁰Th/²³²Th)₀ are observed with variations in SiO₂ and CaO + Al₂O₃ contents, and ⁸⁷Sr/⁸⁶Sr and Dy/Dy* ratios of the lavas. These changes correspond to increasing (²³⁸U/²³²Th) with decreasing Dy/Dy* and CaO + Al₂O₃ ratios, which is attributed to changes in crystallization of mineralogical phases within magmatic chambers during differentiation. Also, ²³⁰Th in-growth is produced during stagnation within magmatic chambers located below the San Pedro-Linzor volcanic chain. Finally, a positive correlation between (²³⁰Th/²³²Th)₀ and ⁸⁷Sr/⁸⁶Sr indicates an important role of crustal contamination, and of new mafic inputs during evolution of the volcanic chain with time. Our observations suggest that better constraints of all magmatic processes are needed to fully understand the U-series disequilibria recognized for the different volcanic structures developed within subduction-related tectonic environments.