UV promoted phenanthridine syntheses from oxime carbonate derived iminyl radicals

Roy T. McBurney; Alexandra M Z Slawin; Laura A. Smart; Yanping Yu; John C. Walton

doi:10.1039/c1cc12720a

UV promoted phenanthridine syntheses from oxime carbonate derived iminyl radicals

Roy T. McBurney^*, Alexandra M Z Slawin, Laura A. Smart, Yanping Yu, John C. Walton

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

116 Citations (Scopus)

Abstract

Oxime carbonates were found to be excellent precursors for the clean and direct generation of iminyl radicals under UV irradiation. Suitably functionalised iminyls underwent cyclisations yielding various phenanthridines and also substituted quinolines and isoquinolines. EPR and X-ray analyses of oxime carbonates provided insight into the mechanism.

Original language	English
Pages (from-to)	7974-7976
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	28
DOIs	https://doi.org/10.1039/c1cc12720a
Publication status	Published - 28 Jul 2011
Externally published	Yes

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title = "UV promoted phenanthridine syntheses from oxime carbonate derived iminyl radicals",

abstract = "Oxime carbonates were found to be excellent precursors for the clean and direct generation of iminyl radicals under UV irradiation. Suitably functionalised iminyls underwent cyclisations yielding various phenanthridines and also substituted quinolines and isoquinolines. EPR and X-ray analyses of oxime carbonates provided insight into the mechanism.",

author = "McBurney, {Roy T.} and Slawin, {Alexandra M Z} and Smart, {Laura A.} and Yanping Yu and Walton, {John C.}",

year = "2011",

month = jul,

day = "28",

doi = "10.1039/c1cc12720a",

language = "English",

volume = "47",

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journal = "Chemical Communications",

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T1 - UV promoted phenanthridine syntheses from oxime carbonate derived iminyl radicals

AU - McBurney, Roy T.

AU - Slawin, Alexandra M Z

AU - Smart, Laura A.

AU - Yu, Yanping

AU - Walton, John C.

PY - 2011/7/28

Y1 - 2011/7/28

N2 - Oxime carbonates were found to be excellent precursors for the clean and direct generation of iminyl radicals under UV irradiation. Suitably functionalised iminyls underwent cyclisations yielding various phenanthridines and also substituted quinolines and isoquinolines. EPR and X-ray analyses of oxime carbonates provided insight into the mechanism.

AB - Oxime carbonates were found to be excellent precursors for the clean and direct generation of iminyl radicals under UV irradiation. Suitably functionalised iminyls underwent cyclisations yielding various phenanthridines and also substituted quinolines and isoquinolines. EPR and X-ray analyses of oxime carbonates provided insight into the mechanism.

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U2 - 10.1039/c1cc12720a

DO - 10.1039/c1cc12720a

M3 - Article

C2 - 21677988

AN - SCOPUS:79959901801

SN - 1359-7345

VL - 47

SP - 7974

EP - 7976

JO - Chemical Communications

JF - Chemical Communications

IS - 28

ER -

UV promoted phenanthridine syntheses from oxime carbonate derived iminyl radicals

Abstract

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